Tomorrow is going to be the second-to-the-last day of my chocolate candies unit at pastry school, and I'm curious enough about this that I'll ask our instructor for any info she can give me on doing a ganache with coconut milk.
Just thinking about it my concern would be that coconut milk, even the thick variety, has significantly less fat in it than the heavy cream that would typically be used for a ganache. I went through some chocolate recipe books that I own, and the only one that I could find with a coconut milk ganache was made from coconut milk, white chocolate, invert sugar, and unsweetened dried coconut. Not much help unless you have a dairy-free white chocolate, and if you did I don't think it would behave the same way as a more typical white chocolate anyway.
For the ganache method it would be hard to go wrong with the old standby of bringing your liquid and any sweetener up to a simmer, pouring it over chocolate that's been melted about halfway, letting it rest 30 seconds or so to melt further, and then whisking in a tight circle in the center of the bowl until you see a nice emulsified core and eventually expanding out to the rim of the bowl. A quick mix with a hand blender at the end would be nice for the consistency of the ganache, but not at all necessary.
As far as other flavors, I'm pretty fond of pairing cardamom with coconut milk. I would take the seeds from 2-3 green cardamom pods and toast them lightly over medium heat until fragrant and then grind them. Bring the coconut milk up to a simmer, remove it from the heat and stir in the ground cardamom, cover your pot with plastic wrap and infuse for maybe 15-30 minutes. Pass the coconut milk through a strainer and put the pot back on the heat, bring it back to a simmer, and then use the ganache method above. You could also add some vanilla, like 1/4 of a bean if you have any (and if so, scrape it out and add it when the cream first goes on the heat).