Culinarily speaking, you get similar results - though I wouldn't put an unopened can in a pressure cooker!
A pressure cooker has a higher boiling point due to the pressure generated by trapping the steam; instead of cooking at 212 degrees, you're cooking at between 215 and 250 degrees. It requires that you cook in a liquid to work, so stews, soups, braising can all be accomplished more quickly than on the stove-top.
A crock-pot, partly through the insulation of the heavy crock and lid, and partly through the heating element, is able to maintain a consistent low temperature for a very long time (
Wikipedia states that
A typical slow cooker operates at (more or less) 80°C (176°F) on low, 90°C (194°F) on high, and 1 hour at 90°C followed by 80°C on medium) It allows you to cook in liquid low and slow, and doesn't require attention, so you can set it up in the morning and forget it until dinnertime.